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ANGELINA JOLIE has sparked a new scandal after confessing she and BRAD PITT fell in love on the set of action movie Mr & Mrs Smith - while the actor was still married to JENNIFER ANISTON.

Despite furious speculation the began their love affair whilst filming the action comedy, the couple have always maintained there was no romance until Brad had split with Friends actress Jen.

The pair have always insisted they just became “very, very good friends” after meeting on the set of the 2005 movie - but now Ange has inadvertently told a different story.